Kundu, Dipali and Roy, S K (1992) Spectrophotometric determination of copper and silver in glass after extraction of dithixonate complexes on polyurethane foam. Transactions of the Indian Ceramic Society, 51 (2). pp. 46-49. ISSN 0371-750X

[img] PDF - Published Version
Restricted to Registered users only

Download (325Kb) | Request a copy

Abstract

A spectrophotometric method has been described for the determination of minor or trace amount of copper and silver when present together in special glasses. The method involves selective extraction of copper dithizonate on polyurethane foam after masking of silver with chloride. Silver is extracted in ammoniacal medium after masking of copper with EDTA. Both the complexes, i.e. copper and silver dithizonates are eluted from foam with acetone. Determinations are carried out spectrophotometrically. Beer's law is obeyed for the concentration range of 0.05–2.5 μg Cu/ml at 550 nm and 0.10–6.0 μg Ag/ml at 500 nm. The method yields agreeable results.

Item Type: Article
Subjects: Microstructure and Characterization
Divisions: UNSPECIFIED
Depositing User: Bidhan Chaudhuri
Date Deposited: 02 Dec 2013 12:14
Last Modified: 05 Mar 2016 14:34
URI: http://cgcri.csircentral.net/id/eprint/2392

Actions (login required)

View Item View Item