Chatterjee, Madhumita and Ghosh, Saktiprosad and Nandi, Asok Kumar (1999) X-ray crystal structure of [VO(DPA)(H2O)(2)]center dot 2H(2)O (DPA = dipicolinate dianion). Transition Metal Chemistry, 24 (2). pp. 183-185. ISSN 0340-4285

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Abstract

The X-ray crystal structure of the trans-diaqua complex [VO(DPA)(H2O2)]. 2H(2)O (I) (DPA = dipicolinate dianion) has been determined. Comparison with the known structure of [VO(DPA)(o-phen)]. 3H(2)O (2), obtained from (1) by displacement of the two coordinated aqua molecules, shows that the coordination sphere around vanadium is reorganised during this reaction.

Item Type:	Article
Subjects:	Crystal Chemistry, Thermodynamics, Phase Equilibria
Divisions:	UNSPECIFIED
Depositing User:	Bidhan Chaudhuri
Date Deposited:	19 Jun 2012 08:00
Last Modified:	20 Jun 2012 10:08
URI:	http://cgcri.csircentral.net/id/eprint/1506

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