Roy Choudhury, C and Dey, S K and Mitra, S and Mondal, N and Ribas, J and Malik, K M A (2004) One novel racemic Cu-Co cyano-bridged complex: synthesis, characterization, crystal structure, and magnetic properties. Bulletin of the Chemical Society of Japan, 77 (5). pp. 959-964. ISSN 0009-2673

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Abstract

One novel racemic Cu–Co cyano-bridged complex [C38H38CoCu2N14O]+[C22H18CoCuN10]−·7H2O where [L = N,N′-bis(2-pyridylmethylene)butane-1,4-diamine] has been prepared and characterized by elemental analyses, spectroscopic study, single crystal X-ray crystallography, and variable temperature magnetic susceptibility measurements. The compound crystallises as a 57/43 racemic twin and contains two different, one binuclear and one trinuclear, complex species. A low temperature magnetic susceptibility measurement showed the existence of very weak antiferromagnetic interactions.

Item Type:	Article
Subjects:	Microstructure and Characterization
Divisions:	UNSPECIFIED
Depositing User:	Bidhan Chaudhuri
Date Deposited:	31 Jan 2012 06:32
Last Modified:	04 Apr 2016 10:37
URI:	http://cgcri.csircentral.net/id/eprint/568

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