Ghosh, Saswati and Kundu, Paritosh and Das Sharma, Abhijit and Basu, Rajendra Nath and Maiti, Himadri Sekhar (2008) Microstructure and property evaluation of barium aluminosilicate glass-ceramic sealant for anode-supported solid oxide fuel cell. Journal of the European Ceramic Society, 28 (1). pp. 69-76. ISSN 0955-2219

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Abstract

Several glass compositions based on the barium aluminosilicate system have been investigated for their application as sealant for solid oxide fuel cell (SOFC). The developed glasses were characterized through measurement of different properties, viz. coefficient of thermal expansion (CTE), glass transition temperature (T-g), dilatometric softening temperature (T-d), crystallization behavior during prolonged heat-treatment, electrical resistivity measurement, microstructural studies, etc. In addition, bonding behavior between zirconia electrolyte and metallic interconnect in sandwiched condition has also been investigated to find out their suitability as sealant for SOFC. Microstructural investigation revealed a well-adhered bonding between the electrolyte and the metallic interconnect. The optimized glass composition also showed a high resistivity (similar to 10(5) Omega cm) at the SOFC operation temperature (similar to 800 degrees C). (c) 2007 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: solid oxide fuel cell; glass-ceramics; electron microscopy; thermal expansion
Subjects: Microstructure and Characterization
Divisions: UNSPECIFIED
Depositing User: Bula Ghosh
Date Deposited: 17 Jan 2012 11:07
Last Modified: 21 May 2012 12:08
URI: http://cgcri.csircentral.net/id/eprint/325

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